Shocking video has emerged showing the moment a brute smacks an NYPD cop in the head with a bottle — before trying to pummel her and her partner.

The new clip, posted on the NYC Scoop Twitter feed, shows the uniformed female cop standing on a busy sidewalk at 231st Street and Broadway in Kingsbridge around 2 p.m. Monday. 

Suddenly, 45-year-old Jose Garcia walks up behind her and clocks her on the side of the head with the bottle. 

He then charges at her and swings at another cop standing next to her before he is taken to the ground by that officer and at least one other person, the footage shows. 

Garcia, of Kingsbridge Heights, was arrested and charged with assault, obstruction of governmental administration, resisting arrest, menacing, criminal possession of a weapon and harassment, police said. 

He has 11 previous arrests, law enforcement sources said.

The injured cop – who was conducting smoke shop inspections with the New York City Sheriff’s Department when she was attacked – was taken to St. Barnabas Hospital, where she was treated and listed in stable condition, according to cops and sources.

She is stationed at a Queens precinct, but was in the Bronx for smoke shop inspections, sources said.

Smoke shops across the city have been illegally pedaling marijuana and other products.